In the moment, the issue was less whether they would help overthrow Joffrey and more whether they would literally stab Ned’s men in the back.
However, I would say that if you look at the history of revolutions and coups, the officer corps is hugely important in deciding the decisions of the rank-and-file, in no small part because the rank-and-file spend a lot of time being trained to obey orders from their officer corps.
So would all of the Gold Cloaks have eagerly joined in Ned’s coup? Probably not. But enough of them would have to give Ned the edge he needed vs. Cersei’s hundred men at arms, and the rest would likely have remained inactive without Slynt’s leadership to give them direction.