Well, the moral philosophy of Mjolnir is a rather complicated subject, and not one I’m super-familiar with.

But…from the research I’ve been able to do, what qualifies one as “worthy” varies a lot from author to author – does it have to do with selflessness and self-sacrifice, or the ideals of ”pure of heart and noble of mind” as understood by the Vikings? Does one have to be a god, or a human, or can a particularly valiant frog/android/other weird thing be worthy?
Personally, I think the hammer twitch thing was a sign that Captain America will wield the hammer at some future moment – probably going shield-and-hammer against Thanos in Infinity War, if I were a betting man – but is not yet worthy. Which would fit in with the history of Cap and Mjolnir in the comics – whenever he’s wielded it in the past, it’s always been in a moment of supreme crisis, where Cap is stepping up to fight Set or some similarly supernaturally evil being.