According to Jaime IV of AFFC, the Freys at Riverrun have 2,000 men and they outnumber Daven’s contingent. So I would say anywhere between 500 and 1500?
As for Volantis, they had 6,000 men just to guard against the Golden Company in Griff I, and they had 300-500 ships according to Victarion. so I would say anywhere between 10-30,000 infantry on those ships (30-100 per ship plus the normal crew).